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61.
Surface microcompression is a very important technique to characterize the mechanical properties of film and coating systems. In this paper, surface microcompression simulation for La2Zr2O7 (LZ) thermal barrier coatings (TBCs) was implemented by finite element method, especially, the influence of pores on the surface microcompression mechanical response of the thermal barrier coatings fabricated by atmospheric plasma spray (APS) was focused on. The simulation results indicate that the pores not only affect the stress distribution beneath the contact area between the indenter and coating surface, but also affect the shape of the force-displacement curve and the plastic deformation behavior of TBCs. The micromechanism was discussed in detail in this study. At the same time, by using the surface microcompression technique, a new direction or method was proposed to characterize the pore content of the coating quantitatively. 相似文献
62.
Hongyan Liu Riguang ZhangFangyuan Ding Ruixia YanBaojun Wang Kechang Xie 《Applied Surface Science》2011,257(22):9455-9460
A density-functional theory method has been conducted to investigate the association of C + O on (1 1 1) facets of ordered NiCo alloy and the results have been compared with those obtained on pure Ni(1 1 1) surface. In reaction of C + O, the favorable reaction path is that C adsorbed on HCP-1 site moves to the nearest Ni-Co bridge site, and associates with O migrating from FCC-1 site to result in CO adsorbed on the bridge site of Ni-Co. However, the reaction barrier is higher by 0.35 eV than that on pure Ni(1 1 1), which indicates that the incorporation of Co into the Ni crystal is not in favor of the reaction of carbon delimination. 相似文献
63.
Hongyan Liu Riguang ZhangRuixia Yan Baojun Wang Kechang Xie 《Applied Surface Science》2011,257(21):8955-8964
A density-functional theory method has been conducted to investigate the adsorption of CHx (x = 0-4) as well as the dissociation of CHx (x = 1-4) on (1 1 1) facets of ordered NiCo alloy. The results have been compared with those obtained on pure Ni (1 1 1) surface. It shows that the adsorption energies of C and CH are decreased while it is increased for CH3 on NiCo (1 1 1) compared to those on pure Ni (1 1 1). Furthermore, on NiCo (1 1 1), dissociation of CHx prefers not to the top of Ni, but to the top of Co. The rate-determining step for CH4 dissociation is considered as the first step of dehydrogenation on NiCo (1 1 1), while it is the fourth step of dehydrogenation on Ni (1 1 1). Furthermore, the activation barrier in rate-determining step is slightly higher by 0.07 eV on Ni (1 1 1) than that on NiCo (1 1 1). From above results, it is important to point out that carbon is easy to form on NiCo (1 1 1) although the adsorption energy of C atom is slightly decreased compared to that on Ni (1 1 1). 相似文献
64.
Digital image correlation approach to cracking and decohesion in a brittle coating/ductile substrate system 总被引:1,自引:0,他引:1
By using a digital image correlation technique, the full/local field strain in a brittle coating/ductile substrate system during tension has been successfully monitored. One of the most important experimental results indicates that the distribution of interfacial shear stress in the segmented coating is antisymmetric about the center, which clarifies several controversial assumptions introduced in theoretical models. Two key mechanical properties of thermal barrier coatings, fracture strength in coating and interfacial adhesion strength, were determined as 35.0 ± 4.6 and 14.1 ± 3.2 MPa, respectively, which are consistent with available experimental data. 相似文献
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66.
在有效质量近似和球形方形势模型下,计算了开放型球状纳米系统电子散射截面及电子按能量的概率分布,探讨了线度、势垒宽度对电子散射截面和共振能量以及共振宽度的影响.结果表明:电子的散射截面随能量的分布曲线有一极大值和极小值,而且电子能量的概率分布曲线的极大值位置总是介于散射截面分布曲线的极大值与极小值的能量位置之间;散射截面随内核半径r0的增大而增大,而且散射截面分布曲线随r0的增大由较平滑变得较尖锐;散射截面随势垒宽度Δ的增大而增大,但在Δ=1.4aCdS–1.7aCdS的范围内,变化出现异常,在Δ=1.6aCdS时散射截面出现极小;电子共振能量El 随Δ的变化与电子所处状态有关,而电子共振宽度Γl随Δ的增大而减小;不论Δ取何值, El和Γl都满足能量和时间的测不准关系.
关键词:
球状纳米系统
势垒宽度
电子散射截面
电子概率分布 相似文献
67.
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70.
BaMnO3 nanorods were synthesized at 200 °C and atmospheric pressure using the composite-hydroxide mediated method. X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy were used to investigate the structure, size, morphology, phase purity and elemental composition of BaMnO3 nanorods. Electrical characterization of BaMnO3 pellet was performed at 300-400 K and in the frequency range 200 Hz-2 MHz. Temperature dependence of AC conductivity suggests that the BaMnO3 pellet behaves as a semiconducting material and conduction across the pellet can be explained by the correlated barrier hopping model. Impedance analysis was performed using the equivalent circuit model (R1Q1C1)(R2C2) and it suggests a single relaxation process in the BaMnO3 pellet at a particular temperature. The analysis reveals that the BaMnO3 pellet behaves like an n-type semiconductor material due to the presence of oxygen vacancies and some disorder. Modulus spectroscopy also supports the impedance results. 相似文献